Metallic Glass Films with Nanostructured Periodic Density Fluctuations Supported on Si/SiO2as an Efficient Hydrogen Sorber

Basit Öğe Kaydı
dc.authoridSarac, A.Sezai/0000-0001-7513-1740
dc.authoridIvanov, Yurii/0000-0003-0271-5504
dc.authoridEckert, Jurgen/0000-0003-4112-3181
dc.authoridPutz, Barbara/0000-0001-9687-6346
dc.authoridGreer, A. Lindsay/0000-0001-7360-5439
dc.authoridSarac, Baran/0000-0002-0130-3914
dc.contributor.authorSarac, Baran
dc.contributor.authorIvanov, Yury
dc.contributor.authorKarazehir, Tolga
dc.contributor.authorPutz, Barbara
dc.contributor.authorGreer, A. Lindsay
dc.contributor.authorSarac, A. Sezai
dc.contributor.authorEckert, Juergen
dc.date.accessioned2025-01-06T17:37:36Z
dc.date.available2025-01-06T17:37:36Z
dc.date.issued2020
dc.description.abstractNanostructured metallic glass films (NMGF) can exhibit surface and intrinsic effects that give rise to unique physical and chemical properties. Here, a facile synthesis and electrochemical, structural, and morphologic characterization of Pd-Au-Si based MGs of approximately 50 nm thickness supported on Si/SiO(2)is reported. Impressively, the maximum total hydrogen charge stored in the Pd-Au-Si nanofilm is equal to that in polycrystalline Pd films with 1 mu m thickness in 0.1 mH(2)SO(4)electrolyte. The same NMGF has a volumetric desorption charge that is more than eight times and 25 % higher than that of polycrystalline PdNF and Pd-Cu-Si NMGF with the same thickness supported on Si/SiO2, respectively. A significant number of nanovoids originating from PdH(x)crystals, and an increase in the average interatomic spacing is detected in Pd-Au-Si NMGF by high-resolution TEM. Such a high amount of hydrogen sorption is linked to the unique density fluctuations without any chemical segregation exclusively observed for this NMGF.
dc.description.sponsorshipEuropean Research Council [ERC-2013-ADG-340025, ERC-2015-ADG-695487]; Austrian Science Fund (FWF) [I3937-N36]; Ministry of Science and Higher Education (Russia) [0657-2020-0005]
dc.description.sponsorshipThe authors thank C. Mitterer and V. Terziyska for providing the sputtering device for synthesizing the MG and Pd nanofilms. This work was supported by the European Research Council under the Advanced Grants INTELHYB-Next generation of complex metallic materials in intelligent hybrid structures (Grant ERC-2013-ADG-340025), ExtendGlass-Extending the range of the glassy state: Exploring structure and property limits in metallic glasses (Grant ERC-2015-ADG-695487), the Austrian Science Fund (FWF) under project grant I3937-N36, and grant 0657-2020-0005 of the Ministry of Science and Higher Education (Russia).
dc.identifier.doi10.1002/chem.202001596
dc.identifier.endpage8253
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.issue37
dc.identifier.pmid32329916
dc.identifier.scopus2-s2.0-85086506794
dc.identifier.scopusqualityQ1
dc.identifier.startpage8244
dc.identifier.urihttps://doi.org/10.1002/chem.202001596
dc.identifier.urihttps://hdl.handle.net/20.500.14669/2299
dc.identifier.volume26
dc.identifier.wosWOS:000540746600001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistry-A European Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241211
dc.subjectelectrosorption
dc.subjecthydrogenation
dc.subjectmetallic glass
dc.subjectnanostructures
dc.subjectthin films
dc.titleMetallic Glass Films with Nanostructured Periodic Density Fluctuations Supported on Si/SiO2as an Efficient Hydrogen Sorber
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu