Effect of boron content on structure and magnetic properties in CoFe2O4 spinel nanocrystals

Basit Öğe Kaydı
dc.authoridKaradag, Faruk/0000-0001-7862-9085
dc.authoridadanur, idris/0000-0002-0160-5074
dc.authoridEkicibil, Ahmet/0000-0003-3071-0444
dc.authoridAkyol, Mustafa/0000-0001-8584-0620
dc.contributor.authorAkyol, Mustafa
dc.contributor.authorAdanur, Idris
dc.contributor.authorAyas, Ali Osman
dc.contributor.authorKaradag, Faruk
dc.contributor.authorEkicibil, Ahmet
dc.date.accessioned2025-01-06T17:44:26Z
dc.date.available2025-01-06T17:44:26Z
dc.date.issued2018
dc.description.abstractWe study the effect of boron content on the structural and magnetic properties of CoFe2O4 spinel nanocrystallines synthesized by sol-gel method. The crystal structure and phase identification of samples are studied by using X-ray diffraction experiment and Rietveld analysis. Rietveld refinement results reveal that all samples have cubic symmetry with space group Fd3m. The cationic distributions are obtained from Rietveld refinement that boron ions are settled into both tetrahedral and octahedral sites in spinel lattice. The crystallite sizes of samples are found in a range of 47-67 nm that is in the limit of single domain in such structure. All samples show ferromagnetic nature and magnetic transition was not seen in the temperature range of 5-400 K. The magnetic domains are pinned with adding boron ions into the CoFe2O4 spinel structure at low temperatures. Thus, an increment in the propagation field (H-p) and temperature (T-p) by boron content in CoFe2O4 structure is observed. In addition, the saturation magnetization (M-s) normalized by crystal size increases with increasing boron concentration. The temperature dependence of magnetic properties of the samples taken by experimental data are confirmed with the Neel-Arhenius model by adding thermal dependence of magnetocrystalline anisotropy term. The results indicate that boron-doping into the spinel structure enhances ferromagnetic coupling and suppresses super-exchange interaction between tetrahedral (X) and octahedral (Y) sites. (C) 2018 Elsevier B.V. All rights reserved.
dc.description.sponsorshipCukurova University (Adana/Turkey) [FBA-2016-6222]
dc.description.sponsorshipThis work was partially supported by Cukurova University (Adana/Turkey) under the Project No. of FBA-2016-6222.
dc.identifier.doi10.1016/j.jallcom.2018.02.121
dc.identifier.endpage534
dc.identifier.issn0925-8388
dc.identifier.issn1873-4669
dc.identifier.scopus2-s2.0-85042064591
dc.identifier.scopusqualityQ1
dc.identifier.startpage528
dc.identifier.urihttps://doi.org/10.1016/j.jallcom.2018.02.121
dc.identifier.urihttps://hdl.handle.net/20.500.14669/3055
dc.identifier.volume744
dc.identifier.wosWOS:000427513400067
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Alloys and Compounds
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241211
dc.subjectSpinel
dc.subjectMagnetism
dc.subjectBoron
dc.subjectNanocrystal
dc.titleEffect of boron content on structure and magnetic properties in CoFe2O4 spinel nanocrystals
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu