Synthesis and Photoluminescence Properties of Eu3+-Activated Ba2Cd(BO3)2 Red-Emitting Phosphors for Near-Ultraviolet Excited White Light-Emitting Diodes

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dc.contributor.authorToreli, S. B.
dc.contributor.authorKafadar, V. E.
dc.contributor.authorEmen, F. M.
dc.contributor.authorOzturk, E.
dc.contributor.authorAltinkaya, R.
dc.date.accessioned2025-04-09T12:32:06Z
dc.date.available2025-04-09T12:32:06Z
dc.date.issued2025
dc.description.abstractA new class of rare-earth doped borate phosphors, Ba2Cd(BO3)(2): xEu(3+) (x = 2, 3, 4, 5, and 6 mol%), was synthesized using the high-temperature solid-state reaction technique in air. X-ray diffraction (XRD) confirmed the phase formation of Ba2Cd(BO3)(2), while Fourier transform infrared spectroscopy (FT-IR) revealed the presence of trigonal [BO3] units. The surface morphology was studied using field emission scanning electron microscopy (FE-SEM), and energy dispersive spectroscopy (EDS) identified the elements. Photoluminescence (PL) analysis showed that the phosphors emitted at 592, 613, 652, and 701 nm, corresponding to the D-5(0) -> F-7(1), D-5(0) -> F-7(2), D-5(0) -> F-7(3), and D-5(0) -> F-7(4) transition of Eu3+ ions, respectively. The 613 nm red emission, from the D-5(0) -> F-7(2) transition, was strongest for the 6 mol% Eu3+ sample. The emission intensity increased with Eu3+ concentration, peaking at 6 mol%. CIE chromaticity, correlated color temperature (CCT), and color purity calculations showed acceptable color coordinates (0.6426 and 0.3548), a low CCT value (2355 K), and high purity (91.34%), making the 6 mol% Eu3+-doped phosphor ideal for red light in white light-emitting diodes (WLEDs).
dc.identifier.doi10.1002/bio.70135
dc.identifier.issn1522-7235
dc.identifier.issn1522-7243
dc.identifier.issue3
dc.identifier.trdizinid40011061
dc.identifier.urihttp://dx.doi.org/10.1002/bio.70135
dc.identifier.urihttps://hdl.handle.net/20.500.14669/4312
dc.identifier.volume40
dc.identifier.wosWOS:001432865200001
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofLuminescence
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20250383
dc.subjectCIE diagram
dc.subjectinorganic borate
dc.subjectphotoluminescence
dc.subjectred phosphor
dc.subjectsolid-state reaction
dc.titleSynthesis and Photoluminescence Properties of Eu3+-Activated Ba2Cd(BO3)2 Red-Emitting Phosphors for Near-Ultraviolet Excited White Light-Emitting Diodes
dc.typeArticle

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