Self-Defined Transition State in Hybrid C70-Au Clusters Created by the Scanning Tunneling Microscope Tip

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dc.authoridAkyol, Mustafa/0000-0001-8584-0620
dc.authoridKaradag, Faruk/0000-0001-7862-9085
dc.authoridKaya, Dogan/0000-0002-6313-7501
dc.authoridEkicibil, Ahmet/0000-0003-3071-0444
dc.contributor.authorKaya, Dogan
dc.contributor.authorWang, Yitao
dc.contributor.authorAkyol, Mustafa
dc.contributor.authorKaradag, Faruk
dc.contributor.authorEkicibil, Ahmet
dc.contributor.authorGuo, Quanmin
dc.date.accessioned2025-01-06T17:45:04Z
dc.date.available2025-01-06T17:45:04Z
dc.date.issued2019
dc.description.abstractManipulation of C-70-Au hybrid nanoclusters was investigated using a scanning tunneling microscope (STM) tip. We demonstrate that removing a selected C-70 molecule from the cluster by STM-tip resulted in an intermediate transition state without thermal decomposition. The molecule rotates and diffuses around the cluster and leaves the cluster without taking an additional molecule and Au atoms due to the rather weak interaction between molecules and the surface atoms. After removing a C-70 molecule, the van der Waals interaction among the remaining C-70 molecules leads to reorganization of the cluster. This self-transition-state is due to a weak charge transfer between the molecules and the surface. The extraction of molecules in a Reshape Transition Interstate ring cluster resulted in polygonal Au island formation.
dc.description.sponsorshipCukurova University [FBA-2018-10813]
dc.description.sponsorshipThis work was supported by Cukurova University Scientific Research Funding Grand No: FBA-2018-10813.
dc.identifier.doi10.1021/acs.jpcc.9b08293
dc.identifier.endpage27950
dc.identifier.issn1932-7447
dc.identifier.issn1932-7455
dc.identifier.issue45
dc.identifier.scopus2-s2.0-85074908057
dc.identifier.scopusqualityQ1
dc.identifier.startpage27945
dc.identifier.urihttps://doi.org/10.1021/acs.jpcc.9b08293
dc.identifier.urihttps://hdl.handle.net/20.500.14669/3284
dc.identifier.volume123
dc.identifier.wosWOS:000497260100073
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Physical Chemistry C
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241211
dc.subjectManıpulatıon
dc.titleSelf-Defined Transition State in Hybrid C70-Au Clusters Created by the Scanning Tunneling Microscope Tip
dc.typeArticle

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