One-pot synthesis of organic-inorganic hybrid polyhedral oligomeric silsesquioxane microparticles in a double-zone temperature controlled microfluidic reactor

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dc.authoridKIBAR, GUNES/0000-0002-2586-6770
dc.authoridcaliskan, umutcan/0000-0001-5982-1493
dc.authoridCetin, Barbaros/0000-0001-9824-4000
dc.contributor.authorKibar, Gunes
dc.contributor.authorCaliskan, Umutcan
dc.contributor.authorErdem, E. Yegan
dc.contributor.authorCetin, Barbaros
dc.date.accessioned2025-01-06T17:37:30Z
dc.date.available2025-01-06T17:37:30Z
dc.date.issued2019
dc.description.abstractPolyhedral oligomeric silsesquioxane (POSS) particles are one of the smallest organosilica nano-cage structures with high multifunctionality that show both organic and inorganic properties. Until now poly(POSS) structures have been synthesized from beginning with a methacryl-POSS monomer in free-radical mechanism with batch-wise methods that use sacrificial templates or additional multisteps. This study introduces a novel one-pot synthesis inside a continuous flow, double temperature zone microfluidic reactor where the methodology is based on dispersion polymerization. As a result, spherical monodisperse POSS microparticles were obtained and characterized to determine their morphology, surface chemical structure, and thermal behavior by SEM, FTIR, and TGA, respectively. These results were also compared and reported with the outcomes of batch-wise synthesis. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1396-1403
dc.description.sponsorshipAdana Science and Techonolgy University Scientific Research Project [17103007]; Turkish Academy of Sciences through Outstanding Young Scientist Program (TUBA-GEBIP); Science Academy Distinguished Young Scientist Award (BAGEP)
dc.description.sponsorshipFinancial support from Adana Science and Techonolgy University Scientific Research Project (Grant No. 17103007) is greatly appreciated. Barbaros Cetin would like to acknowledge funding from the Turkish Academy of Sciences through Outstanding Young Scientist Program (TUBA-GEBIP) and Science Academy Distinguished Young Scientist Award (BAGEP).
dc.identifier.doi10.1002/pola.29399
dc.identifier.endpage1403
dc.identifier.issn0887-624X
dc.identifier.issn1099-0518
dc.identifier.issue13
dc.identifier.scopus2-s2.0-85065331766
dc.identifier.scopusqualityN/A
dc.identifier.startpage1396
dc.identifier.urihttps://doi.org/10.1002/pola.29399
dc.identifier.urihttps://hdl.handle.net/20.500.14669/2241
dc.identifier.volume57
dc.identifier.wosWOS:000472579600003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241211
dc.subjectdispersion polymerization
dc.subjecthybrid microparticles
dc.subjectmicrofluidic reactor
dc.subjectmicroparticle synthesis
dc.subjectmicroreactor
dc.subjectnanocluster
dc.subjectorganosilica
dc.subjectPOSS
dc.subjectthermal control
dc.titleOne-pot synthesis of organic-inorganic hybrid polyhedral oligomeric silsesquioxane microparticles in a double-zone temperature controlled microfluidic reactor
dc.typeArticle

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