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Öğe Changes in bioactive properties of dry bean extracts during enzymatic hydrolysis and in vitro digestion steps(Springer, 2022) Aydemir, Levent Yurdaer; Diblan, Sevgin; Aktas, Havva; Cakitli, GamzeDue to good protein quality and beneficial nutritional contents, dry beans have potential to be processed as functional food ingredients. Therefore, phenolic content, free radical scavenging (FRSA), iron chelating (ICA), antidiabetic, antihypertensive, and antimicrobial activities of flour (BF), hydrocolloid extract (BHE) and high protein content extracts (BP1 and BP2 - aided dilute salt) of common bean were determined after in vitro digestion (gastric and intestinal) process and Alcalase and Savinase hydrolysis. The highest ICA (27.94 +/- 0.52 mg EDTA/g) and antihypertensive activity (66.8% ACE inhibition) by BP2; antidiabetic activity (between 63.7 +/- 6.0 and 83.5 +/- 1.0% alpha-glucosidase inhibition, 46.2 +/- 2.5 and 46.3 +/- 0.8% alpha-amylase inhibition) by BF and BHE; phenolic content (113 +/- 4 mg GA/g and 96 +/- 1 mg quercetin/g) and FRSA (1807 +/- 150 mu mol Trolox/g) by BP1 and antimicrobial activity (E. coli, S. aureus) by BP1 and BP2 was determined after in vitro digestion. Alcalase enzyme produced dry bean hydrolysates with higher phenolic content, FRSA and ICC but caused in antidiabetic activity during hydrolysis process (except for BHE hydrolysates) while Savinase produced bioactive peptides with high alpha-amylase and alpha-glucosidase inhibition activity. Alcalase also generated antimicrobial peptides against L. monocytogenes, S. aureus, and E. coli. The study showed the high potential of dry bean to be processed for functional food ingredient. It was also stated that the applied extraction method was critical to obtain the bioactive components from dry bean seeds.Öğe Characterization of biodegradable films based on guar gum and calcium caseinate incorporated with clary sage oil: Rheological, physicochemical, antioxidant, and antimicrobial properties(Elsevier, 2024) Bhatia, Saurabh; Shah, Yasir Abbas; Al-Harrasi, Ahmed; Alhadhrami, Aysha Salim; Alhashmi, Dalal Sulaiman Hamed; Jawad, Muhammad; Diblan, SevginClary sage essential oil (CSEO) has been reported for its wide food and pharmaceutical applications. This work aimed to produce biodegradable active guar gum-calcium caseinate (GG-CC) based film incorporated with CSEO and to evaluate its physico-chemical, antioxidant, and antibacterial properties. Solvent casting technique was used to prepare the composite films containing CSEO at 0.1, 0.15, and 0.2% (v/v). The chemical, rheological, morphology, mechanical, thermal, optical, crystalline, biodegradable, water barrier, antioxidant and antimicrobial potential of the samples were assessed by various analytical methods. Rheological findings of filmogenic solution revealed that the viscosity of filmogenic solutions (GCEO2-GCEO4) increased with an increase in the concentration of the CSEO. CSEO addition in GG-CC film exhibited a homogenous structure with low crystallinity, transparency, water vapor permeability, moisture content, and tensile strength values, whereas a rise in elongation at break, thickness, and thermal stability was observed. Fourier transforms infrared (FTIR) results suggested the interaction between CSEO and GG-CC-CSEO films also exhibited satisfactory antioxidant activity against DPPH and ABTS free radicals and higher antimicrobial effect against the Gram-negative bacteria (Pseudomonas aeruginosa). This work revealed that CSEO has the potential to be used as an active ingredient in the development of films for food packaging applications.Öğe Degradation kinetics of bioactive compounds and antioxidant activity in strawberry juice concentrate stored at high and low temperatures(Springer, 2020) Menevseoglu, Ahmed; Diblan, Sevgin; Turkyilmaz, Meltem; Ozkan, MehmetIn this study, changes in ascorbic acid (AA), phenolics, anthocyanins (ACNs) and antioxidant activity (AOA) were monitored during storage at - 25, 4, 10 and 20 degrees C to observe the stability of bioactive compound in strawberry juice concentrates (SJCs). Half-life periods (t(1/2)) for ACN and AA degradations were 7.9 and 50 days at 20 degrees C, respectively. On the contrary, much higher t(1/2)values were found for the reduction in AOA and phenolics, i.e. 251 and 430 days at 20 degrees C, respectively. AOA and phenolics were more stable during storage than AA and ACNs.p-Coumaric acid was the major phenolic identified in SJC.p-coumaric acid (33.8%), catechin (23.1%), vanilic acid (18.6%) and epicatechin (16.1%), which constituted 91.6% of phenolics in SJC, followed by chlorogenic acid (4.9%) and caffeic acid (3.2%). Chlorogenic acid was the least stable phenolic in SJC stored at 20 degrees C. Strong correlations were found between AOA and ACNs (r = 0.99), phenolics (r = 0.94) and AA (r = 0.92) in SJC stored at 20 degrees C. Significant ACN and AA degradations occurred at storage temperature as low as 4 degrees C. Therefore, storage at - 25 celcius was suggested for SJC to maximize the stabilities of especially ACNs and AA in SJC.Öğe Development and structural assessment of whey protein isolate/sunflower seed oil biocomposite film(Elsevier, 2019) Erdem, Burcu Gokkaya; Diblan, Sevgin; Kaya, SevimThe overall aim of this research was to investigate effect of sunflower oil addition on formation of whey protein based biocomposite edible films. The biocomposite films were prepared through an emulsion technique by dispersing three different ratios of sunflower oil (0.05%, 0.10% and 0.15%) in whey protein isolate medium. Moisture content, solubility in water, water sorption kinetic, swelling index, contact angle, color, whiteness, and opacity index of the films were examined. Thermal, barrier, and mechanical properties were tested. Particle size distribution and surface microstructure of the films were also analyzed. The moisture content of the biocomposite films was not affected with sunflower oil addition but the solubility showed reducing tendency. Increasing oil content increased contact angle. Although color parameters, whiteness index, and total color were not affected significantly by oil addition whereas the opacity index of the biocomposite films was determined to be higher than the control film (no sunflower oil present). Glass transition value of the control film was significantly lower than those of emulsified films (p <0.05). All of the film forming emulsions showed bimodal particle size distribution with two major peaks. The results showed that despite the low oil amount in biocomposite film composition, oil addition had a positive effect on the water vapor and oxygen barrier properties of the films. It was understood that low amount of sunflower oil increased the hydrophobic property of the films without any adverse change in the barrier and optical characters of the films. (C) 2019 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.Öğe Effects of various clarification treatments on anthocyanins, color, phenolics and antioxidant activity of red grape juice(Elsevier Sci Ltd, 2021) Diblan, Sevgin; Ozkan, MehmetLow turbidity and low discolouration is targeted in clear red grape juice (RGJ) production. Depending on type of clarification agents, substantial discolouration may occur. Therefore, this study was undertaken to show effects of various clarification treatments (bentonite and chitosan, and combinations of ?bentonite + gelatin (B + G),? ?bentonite + casein (B + CA),? ?bentonite + albumin (B + A)? and ?bentonite + chitosan (B + CTS)? on turbidity, color (ACNs, color density-CD and polymeric color-PC), phenolics and antioxidant activity (AOA) during RGJ clarification. Casein alone (4.0 NTU and 9.1% ACN loss) and in combination with bentonite (4.4 NTU and 12.3% ACN loss), followed by B + A (5.7 NTU and 12.3% ACN loss) resulted in best clarity and was associated with least change in ACNs. These clarifications also resulted in high CD (intensive red color) and low PC (low browning). At all dosages, gelatin and albumin were associated with highest ACN losses, while casein in greatest retention. ?Bentonite + casein,? followed by ?bentonite + albumin,? achieved the best clarification of Low turbidity and low discolouration is targeted in clear red grape juice (RGJ) production. Depending on type of clarification agents, substantial discolouration may occur. Therefore, this study was undertaken to show effects of various clarification treatments (bentonite and chitosan, and combinations of ?bentonite + gelatin (B + G),? ?bentonite + casein (B + CA),? ?bentonite + albumin (B + A)? and ?bentonite + chitosan (B + CTS)? on turbidity, color (ACNs, color density-CD and polymeric color-PC), phenolics and antioxidant activity (AOA) during RGJ clarification. Casein alone (4.0 NTU and 9.1% ACN loss) and in combination with bentonite (4.4 NTU and 12.3% ACN loss), followed by B + A (5.7 NTU and 12.3% ACN loss) resulted in best clarity and was associated with least change in ACNs. These clarifications also resulted in high CD (intensive red color) and low PC (low browning). At all dosages, gelatin and albumin were associated with highest ACN losses, while casein in greatest retention. ?Bentonite + casein,? followed by ?bentonite + albumin,? achieved the best clarification of RGJ.Öğe Gelatin/calcium-caseinate films loaded with petitgrain essential oil for sustainable food packaging(Wiley, 2024) Bhatia, Saurabh; Shah, Yasir Abbas; Al-Harrasi, Ahmed; Jawad, Muhammad; Diblan, Sevgin; Khan, Talha Shireen; Koca, EsraThis research focuses on the development and assessment of films composed of gelatin (GE) and calcium caseinate (CC), loaded with varying concentrations of petitgrain essential oil (PEO). A comprehensive assessment of the resulting films was conducted with a focus on the antioxidant, antibacterial, and physicochemical attributes. GCMS analysis identified the primary constituents of PEO, including linalyl acetate, linalool, alpha-pinene, alpha-terpineol, limonene, beta-myrcene, geranyl acetate, and neryl acetate. The antioxidant capacity of GE-CC films increased significantly with increasing PEO concentration, as evidenced by DPPH and ABTS assays. Simultaneously, increased PEO concentration led to increased thickness, water vapour permeability (WVP), elongation at break (EAB), and water solubility (WS) in the active films while reducing moisture content (MC) and tensile strength (TS). In terms of optical characteristics, the transparency of the films decreased, while the b* (yellowness) and Delta E (total colour variation) values increased upon oil incorporation. The presence of intermolecular interactions between the polymers and the oil was confirmed through FTIR and morphological characteristics studied by SEM. The addition of PEO to the films resulted in improved thermal resistance against degradation, as observed in the thermo-gravimetric analysis (TGA). Moreover, these active films showed potent antimicrobial activity against C. albicans and P. aeruginosa. In summary, this study underscores the suitability of GE-CC films containing PEO for food packaging purposes, highlighting their functional characteristics and environmentally friendly nature. Visual analysis of gelatin and calcium caseinate blank and composite films loaded with and without varying concentrations of petitgrain essential oil. Film samples loaded with and without oil exhibited homogeneous and even structures without any irregularities, demonstrating the good film-forming properties of the biopolymers as well as their compatibility with other components. imageÖğe Impact of conjugation of whey protein concentrate with different carbohydrates: Monitoring structural and technofunctional variations(Elsevier Sci Ltd, 2024) Diblan, Sevgin; Salum, Pelin; Ulusal, Fatma; Erbay, ZaferThis study utilized whey protein concentrate (WPC) as the primary protein source, employing the Maillard reaction to link it with three distinct carbohydrates: lactose, maltodextrin, and gum Arabic. Mixtures were prepared with a 1:4 protein-to-carbohydrate ratio, and conjugation was performed using dry heating at a temperature of 60 degrees C, 50% relative humidity for 8 h processing time. Under the same conditions, native WPC was heated as a control group. The formation of conjugates was tracked by monitoring absorbance changes, browning index (BI), and reduction in free amino groups (FAG). All conjugates exhibited significant loss of FAG, correlating with an increase in BI. Shifts in protein fingerprint bands observed via Fourier Transform Infrared Spectroscopy suggested potential protein-carbohydrate interactions, while X-ray diffraction showed increased sample crystallinity post-conjugation. Solubility assessments across pH levels (3.0-8.0) indicated a 10-13% rise in solubility for conjugated samples compared to mixtures, broadening their potential applications. Moreover, the emulsion stability index demonstrated improved stability after conjugation. Overall, the Maillard reaction-mediated conjugation enhanced the solubility and stability of emulsions.Öğe Impregnation of Pectin-Sodium Caseinate Films with Lemongrass Essential Oil: Physical-Chemical, Antimicrobial, and Antioxidant Assessment(Amer Chemical Soc, 2024) Bhatia, Saurabh; Khan, Talha Shireen; Alhadhrami, Aysha Salim; Shah, Yasir Abbas; Philip, Anil K.; Diblan, Sevgin; Koca, EsraBiopolymers derived from natural resources have gained much interest in the past few decades to replace conventional nonbiodegradable petroleum-based packaging. Essential oils and plant extracts are frequently utilized for their antimicrobial and antioxidant properties in the development of edible films and coatings serving as bioactive compounds. The current study investigated the impact of various concentrations of lemongrass essential oil (LEO) on the physical and chemical characteristics as well as the antioxidant capabilities of films made from sodium caseinate and pectin. The addition of LEO led to a decrease in mechanical parameters of film samples like elongation at break (EAB) decreased from 19.73 +/- 0.81 to 4.06 +/- 0.20 and tensile strength (TS) decreased from 11.16 +/- 0.81 to 2.43 +/- 0.08 but a rise in opacity (4.39 +/- 0.14 to 5.60 +/- 0.13), thickness (0.044 +/- 0.005 to 0.078 +/- 0.005), and water vapor permeability (WVP) (0.391 +/- 0.013 to 0.760 +/- 0.035) was observed. The gloss value of the film samples increased from 11.9 +/- 0.1 to 13.1 +/- 0.1, and haziness increased from 45.85 +/- 1.05 to 71.69 +/- 0.25 as the concentration of LEO increased, reducing their transparency (89.22 +/- 0.27-88.24 +/- 0.19). Scanning electron microscopy (SEM) revealed additional microstructural alterations in the films as a result of the addition of LEO. Furthermore, antimicrobial activity was detected in the PSC4 film sample against E. coli. The oil-loaded films showed significantly higher antioxidant activity of 40.41% compared to the control film sample, having 16.57% antioxidant activity. Contact angle measurements demonstrated that the film samples became more hydrophobic with the addition of LEO (55.52 degrees in the maximum LEO concentrated film). This study introduces a promising method for creating active food packaging materials for packaging applications.Öğe Influence of processing steps on phenolic composition of clarified and unclarified pomegranate juices as characterized by LC-DAD-ESI-MS/MS(Wiley, 2019) Davarci, Arife; Kadiroglu, Pinar; Diblan, Sevgin; Selli, Serkan; Kelebek, HaşimIn this study, quality parameters of clarified (CPJ) and unclarified pomegranate juices (UPJ) of Hicaz variety (obtained from industrial-scale fruit juice production plant) were investigated regarding general compositions (sugar, organic acid, color parameters, etc.), phenolic content and also antioxidant capacity. The predominant anthocyanin was detected as cyanidin-3,5-diglucoside followed by cyanidin-3-glucoside, delphinidin-3,5-diglucoside, delphinidin-3-glucoside, pelargonidin-3-glucoside, cyanidin pentoxide, pelargonidin-3,5-diglucoside. Cyanidin pentoxide was detected for the first time in this study in pomegranate juices in Turkey. During production, a decrease was observed in anthocyanins up to 39%. Fourteen colorless phenolic compounds were identified as primary ellagic acid, punicalagin-alpha, and punicalagin-beta. The most significant decrement in phenolic compounds was observed in clarification/filtration steps of CPJ and separation step of UPJ while an increase was detected after pressing. However, the reduction of phenolic content of CPJ was higher than UPJ during production. This decrease was probably related to the effect of clarification agents, filtration, and evaporation processes. Practical applications Pomegranate juices have high nutritional value and health benefits with its rich content of phenolic compounds. Processing steps of unclarified and clarified pomegranate juices production could lead to differences in phenolic compounds and other bioactive properties. This study contributes valuable information for industrial production of pomegranate juices.Öğe Pectin/sodium alginate films tailored with Acetyl-11-keto-beta-boswellic acid for active packaging(Elsevier, 2024) Bhatia, Saurabh; Shah, Yasir Abbas; Al-Harrasi, Ahmed; Jawad, Muhammad; Khan, Talha Shireen; Alam, Tanveer; Diblan, SevginThe present study aimed to develop food packaging films by using a combination of pectin (PE) and sodium alginate (SA) enriched with Acetyl-11-keto-beta-boswellic acid (AKBA) as a functional or active ingredient. The fabricated films underwent comprehensive evaluation of their morphological, chemical, mechanical, barrier, optical, thermal, antioxidant, and antimicrobial properties. SEM and FTIR analysis showed that AKBA had good compatibility with film-forming components. The AKBA-loaded film samples exhibited a decrease in their barrier properties and tensile strength, but enhancements in both elongation at break and thickness values was observed. With the addition of AKBA, a significant increase (p < 0.05) in the ultraviolet barrier properties of the films and total colour variation (Delta E) was observed. TGA analysis of the films unveiled an improvement in thermal resistance with the incorporation of AKBA. Moreover, the films loaded with AKBA exhibited potent antioxidant activity in the ABTS and DPPH assay methods. Disk diffusion analysis showed the antimicrobial activity of AKBAloaded films against P. aeruginosa, highlighting the potential of AKBA as a natural antimicrobial agent for the safety of food products. The results demonstrate the practical application of PE and SA active films loaded with AKBA, particularly within the food packaging industry.Öğe Potassium sorbate diffusion in multilayer polymer films: Effects of water activity and pH(Wiley, 2018) Diblan, Sevgin; Kaya, SevimThe main aim of this study was to estimate the effect of acidity and water activity (a(w)) on the diffusion of potassium sorbate (PS) into model aqueous systems at 25 degrees C from an industrially produced multilayer active film (LPDE/polyamide/LPDE containing 2%PS). The releases of PS from films were set according to two factors face-centered central composite design of the response surface method (RSM). The ANOVA, 3D response surface, and 2D contour plots showed that pH and a(w) were effective factors in the diffusion coefficient (D) of PS from the films, and these two variables had an important interaction between them. Film samples within the liquid medium with low a(w) and pH values had the highest D. This might have occurred owing to the swelling of films within the solution with lower a(w) and high solubility of PS, and within the solution having lower pH, the faster diffusion of PS might have occurred. Practical applicationsIn this study, the diffusion kinetic of potassium sorbate was observed under various conditions, such as pH and water activity. These conditions are the most important physico-chemical properties for food products. Moreover, the efficiency of the sorbate depends on the pH of the medium; with increasing pH, the efficiency is decreased, and above pH=6.5, sorbic acid loses its antimicrobial property. Thus, the pH level is very important for the application of such films. Furthermore, these properties can affect both food product specialists and antimicrobial agent release. The pH and water activity were found to be very effective in diffusion kinetics of potassium sorbate. The results showed that antimicrobial diffusion from an active packaging film should be evaluated according to the food properties. We also observed adverse changes in the film structure, especially at lower water activity values. It was possible to relate the effect of a(w) on diffusion with the characteristics of film, the incorporated agents, and the used system. Depending on the diffusion medium, the film structure might change, and this could accelerate or limit the migration.Öğe Sorption, diffusivity, permeability and mechanical properties of chitosan, potassium sorbate, or nisin incorporated active polymer films(Springer India, 2020) Diblan, Sevgin; Erdem, Burcu Gokkaya; Kaya, SevimThe active multilayer packaging films were formed from low-density polyethylene (LDPE) and polyamide containing a 2% antimicrobial agent in one of the LDPE sides of the film (LDPE/polyamide/LDPE-2% antimicrobial agent). The antimicrobial agents used were potassium sorbate (PS-film), nisin (N-film), or chitosan (CTS-film). The effects of antimicrobial incorporation on water vapor permeability (P), diffusivity (D-eff), and solubility (S-o and S-H) of the active and control films (LDPE/polyamide/LDPE) were investigated. A dynamic vapor sorption analyzer (DVS) was used to estimate the sorption isotherms of the films at 25 degrees C. Peleg was found to be the best equation to describe sorption behaviors. The addition of PS and nisin into the film matrix resulted in a lower P than that of the control film. The D-eff values of the active films were lower than those of control films, except for the CTS-film. The high water-holding capacity of PS and nisin might limit the D-eff of the respective films. It was found that Henry's law was applicable to relate P, D-eff, and S-o and S-H values of the multilayer film [correlation coefficient (r) = 0.909-0.971]. The mechanical and thermal properties of the active films were not significantly affected by the incorporation of PS and nisin (p > 0.05). However, the impact of stress and elongation (transverse direction) on the CTS-film was lower than on other films, which indicated that chitosan improved the mechanical properties of the film.Öğe The Applications of Lime (Citrus aurantifolia) Essential Oil as a Functional Ingredient in Gelatin/Kappa-Carrageenan Composite Films for Active Packaging(Amer Chemical Soc, 2024) Shah, Yasir Abbas; Bhatia, Saurabh; Al-Harrasi, Ahmed; Naseer, Aaisha; Jawad, Muhammad; Khan, Talha Shireen; Diblan, SevginGelatin and kappa-carrageenan (GEKC) composite films were developed by incorporating lime essential oil (LEO). GCMS analysis revealed the primary constituents within the LEO, which included limonene, gamma-terpinene, cyclohexene, terpineol, beta-pinene, and geranyl acetate. The oil-loaded films exhibited antimicrobial activity against foodborne pathogens such as Candida albicans and Staphylococcus aureus. DPPH and ABTS assays confirmed the enhanced antioxidant properties of the films. It was observed that the inclusion of LEO led to an increase in film thickness and water permeation, while the mechanical characteristics including tensile strength and elongation decreased with LEO addition. The compatibility of LEO with the film matrix was confirmed via scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Furthermore, the films exhibited improved thermal resistance upon the addition of LEO. This research highlights the potential of LEO as a natural and sustainable antimicrobial and antioxidant agent, paving the way for its application in active packaging.
