Effect of Supporting Electrolyte on Capacitance and Impedance Properties of Electrodeposited PEDOT/ERGO Electrodes for Supercapacitor

dc.contributor.authorKarazehir, Tolga
dc.date.accessioned2025-01-06T17:23:33Z
dc.date.available2025-01-06T17:23:33Z
dc.date.issued2023
dc.departmentAdana Alparslan Türkeş Bilim ve Teknoloji Üniversitesi
dc.description.abstractIn this study, the ability of Poly (3,4-ethylenedioxythiophene)/electrochemically reduced graphene oxide (PEDOT/ERGO) electrodes for supercapacitors to store electrical energy is studied. PEDOT/ERGO electrodes are produced using a simple two-step electrochemical method that involves electrochemically reduction of graphene oxide, and then PEDOT is electrochemically deposited onto the ERGO in different electrolyte solutions. Electrochemical techniques such as cyclic voltammetry (CV), galvanostatic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS) are utilized to investigate the electrochemical characteristics of PEDOT/ERGO electrodes produced in different electrolyte systems including 0.1 M lithium perchloride/acetonitrile (LiClO4/ACN), tetraethylammoniumtetrafluoroborate/acetonitrile (Et4NBF4/ACN), and tetrabutylammonium hexaflorophosphate/acetonitrile (Bu4NPF6/ACN). The electrolyte type has a significant impact on electrochemical results. PEDOT/ERGO manufactured in LiClO4/ACN demonstrates a high specific capacitance (Csp) and low charge transfer resistance (Rct). According to results, the Csp value is decreased in the following order; 26.48 mFcm-2 for LiClO4, 20.58 mFcm-2 for Et4NBF4, 8.96 mFcm-2 for Bu4NPF6.
dc.identifier.doi10.47495/okufbed.1218141
dc.identifier.endpage872
dc.identifier.issn2687-3729
dc.identifier.issue1
dc.identifier.startpage854
dc.identifier.trdizinid1205363
dc.identifier.urihttps://doi.org/10.47495/okufbed.1218141
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/1205363
dc.identifier.urihttps://hdl.handle.net/20.500.14669/820
dc.identifier.volume6
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofOsmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi (Online)
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241211
dc.subjectGraphene
dc.subjectsupercapacitor
dc.subjectPoly(3-4 ethylenedioxy thiophene)
dc.titleEffect of Supporting Electrolyte on Capacitance and Impedance Properties of Electrodeposited PEDOT/ERGO Electrodes for Supercapacitor
dc.typeArticle

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