A novel molecular imprinting polymer for the selective adsorption of D-arabinitol from spiked urine

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dc.contributor.authorRetnanıngtyas, Yuni
dc.contributor.authorSuprıyanto, Ganden
dc.contributor.authorPuspanıngsıh, Ni Nyoman Trı
dc.contributor.authorIrawan, Roedi
dc.contributor.authorSıswandono, Siswandono
dc.date.accessioned2025-01-06T17:23:32Z
dc.date.available2025-01-06T17:23:32Z
dc.date.issued2020
dc.departmentAdana Alparslan Türkeş Bilim ve Teknoloji Üniversitesi
dc.description.abstractIn this research, molecular imprinting polymers (MIPs) for D-arabinitol were synthesized using a bulk\rpolymerization method through a noncovalent approach. The MIPs were prepared by using D-arabinitol as a template,\racrylamide as a functional monomer, ethylene glycol dimethacrylateas cross-linker, benzoyl peroxide as an initiator and\rdimethyl sulfoxideas a porogen. MIPS was synthesized in several formulas with a different molar ratio of template to\rfunctional monomers and cross-linker. Fourier-transform infrared spectroscopy (FT-IR) and scanning electron microscopy\r(SEM) were used to characterize the MIPs produced. A batch rebinding assay was used to test the binding efficiency of\reach formula. Batch rebinding test results revealed that MIPsF3 with a molar ratio of the template: monomer and crosslinker ratio respectively (1: 4: 25) had the highest binding capacity at 1.56 $mgg ^{?1}$. The results of isotherm adsorption\rshowed that the MIPs produced followed the Freundlich equation with an R-value of 0.97. The MIPs produced was also\rselective toward its isomeric compounds (i.e. L-arabinitol, adonitol, xylitol, and glucose). The extraction efficiency of\rthe MIPs against D-arabinitol was 88.98%.
dc.identifier.doi10.3906/kim-2002-56
dc.identifier.endpage1277
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue5
dc.identifier.startpage1265
dc.identifier.trdizinid523102
dc.identifier.urihttps://doi.org/10.3906/kim-2002-56
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/523102
dc.identifier.urihttps://hdl.handle.net/20.500.14669/795
dc.identifier.volume44
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241211
dc.titleA novel molecular imprinting polymer for the selective adsorption of D-arabinitol from spiked urine
dc.typeArticle

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