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    Characterization of Aroma-Active Compounds, Phenolics, and Antioxidant Properties in Fresh and Fermented Capers (Capparis spinosa) by GC-MS-Olfactometry and LC-DAD-ESI-MS/MS
    (Wiley, 2019) Sonmezdag, Ahmet Salih; Kelebek, Hasim; Selli, Serkan
    Caper (Capparis spinosa) is an important food ingredient whose fresh parts, particularly the flower buds, are consumed as a starter with olives, cheese, and nuts, or are used as a component in other foods. It is one of the most popular species of aromatic plants grown in the Mediterranean zone. Fermentation makes the caper edible and affects the overall aroma as well as sensory and nutritional characteristics. This study aimed to evaluate the changes in aroma, aroma-active, and phenolic compounds of caper as affected by fermentation. Purge and trap method was used for the extraction of the aroma compounds, while gas chromatography-mass spectrometry olfactometry and Liquid chromatography coupled to diode array detection and electrospray ionization tandem mass spectrometry (LC-DAD-ESI-MS/MS) were employed for the detection of aroma-active compounds and phenolics, respectively. The results showed that the total amount of aroma compounds decreased drastically (62,616 to 21,471 mu g/kg) in fermented sample. Twelve and 10 aroma-active compounds were detected in fresh and fermented caper buds, respectively, for the first time by the application of aroma extract dilution analysis. Among these compounds, methyl isothiocyanate (flavor dilution [FD] factor = 512) in fresh caper and acetic acid (FD factor = 128) in the fermented caper had the highest FD factor. With regard to the phenolic compounds, a total of 16 components were identified in fresh and fermented capers. As observed in aroma compounds, the total phenolic concentration decreased as a result of fermentation. Two phenolic compounds being kaempferol-3-O-glucosyl-rhamnosyl-glucoside and isorhamnetin hexoside were newly identified in caper. Practical Applications Capparis spinosa is one of the most popular sources of different secondary metabolites of interest to consumers. The results of the present study showed that the fermentation process of the capers is highly influential on the neutral composition of the sample. The total concentrations of aroma and phenolic compounds were reduced by 66% and 78%, respectively, in response to fermentation process.
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    Comparison of aroma, aroma-active, and phenolic compounds of crude and refined hazelnut oils
    (Wiley, 2022) Kesen, Songul; Sonmezdag, Ahmet Salih; Kelebek, Hasim; Selli, Serkan
    Hazelnut (Corylus avellana L.) is an important shelled nut with its pleasant aroma. The refining process causes significant changes in the quality attributes of hazelnut oil. The aim of this study was to assess the aroma, aroma-active, and phenolic compounds of the crude and refined hazelnut oils by using gas chromatography-mass spectrometry (GC-MS), GC-MS-olfactometry (GC-MS-O), and liquid chromatography-mass spectrometry (LC-MS/MS). The antioxidant capacities were also determined by DPPH and ABTS methods. Results showed that terpenes and aldehydes constituted a significant portion of the aroma profile. Refining process dramatically reduced the numbers (from 63 to 25) and amounts of aroma compounds (from 36,769 to 4461 mu g/kg). Similarly, the numbers of aroma-active compounds were reduced from 22 to 8 by the refining process. Their flavor dilution factors ranged from 2 to 1024 for crude oil and from 2 to 32 in the refined oil. As of the phenolics, five and two compounds were quantified in the crude and refined oil samples, respectively. In sum, the refining process had a considerable adverse effect on the aroma, aroma-active, and phenolic constituents of the hazelnut oil; hence, the refining process has to be planned with minimal negative effect on its organoleptic properties.
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    Identification of Aroma Compounds of Lamiaceae Species in Turkey Using the Purge and Trap Technique
    (Mdpi, 2017) Sonmezdag, Ahmet Salih; Kelebek, Hasim; Selli, Serkan
    The present research was planned to characterize the aroma composition of important members of the Lamiaceae family such as Salvia officinalis, Lavandula angustifolia and Mentha asiatica. Aroma components of the S. officinalis, L. angustifolia and M. asiatica were extracted with the purge and trap technique with dichloromethane and analyzed with the gas chromatography-mass spectrometry (GC-MS) technique. A total of 23, 33 and 33 aroma compounds were detected in Salvia officinalis, Lavandula angustifolia and Mentha asiatica, respectively including, acids, alcohols, aldehydes, esters, hydrocarbons and terpenes. Terpene compounds were both qualitatively and quantitatively the major chemical group among the identified aroma compounds, followed by esters. The main terpene compounds were 1,8-cineole, sabinene and linalool in Salvia officinalis, Lavandula angustifolia and Mentha asiatica, respectively. Among esters, linalyl acetate was the only and most important ester compound which was detected in all samples.
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    The most aroma-active compounds in shade-dried aerial parts of basil obtained from Iran and Turkey
    (Elsevier, 2018) Sonmezdag, Ahmet Salih; Amanpour, Armin; Kelebek, Hasim; Selli, Serkan
    Volatile profile, aroma-active compounds and odor activity values of the shade-dried aerial parts of basil (Ocimum basilicum) were investigated. Basil samples used under the study were provided from Iran and Turkey. Volatile compounds were isolated using a purge and trap extraction system and analyzed by gas chromatography olfactometry. A total of 50 volatile compounds of which 29 originated from Iranian and 32 were of Turkish origin were determined. Terpenes were present at the overwhelmingly highest levels, followed by alcohols and aldehydes. Of the terpenes, methyl chavicol was the main compound of both samples. The aroma-active compounds of basils were investigated by using aroma extract dilution analysis (AEDA) for the first time. The application of AEDA revealed 18 aroma-active compounds, including terpenes (10), aldehydes (3), ketone (1), phenol (1), alcohol (1), and unknown compounds (2) were detected. Linalool and methyl chavicol had the greatest flavour dilution (FD) factors in both samples, amounting to 2048 and 1024, respectively.
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    Volatile and key odourant compounds of Turkish Berberis crataegina fruit using GC-MS-Olfactometry
    (Taylor & Francis Ltd, 2018) Sonmezdag, Ahmet Salih; Kelebek, Hasim; Selli, Serkan
    This research was conducted to identify the aroma and aroma-active compounds of Berberis crataegina for the first time. Volatile profile of B. crataegina was obtained using the purge and trap extraction method with dichloromethane. Gas chromatography was coupled to mass spectrometry (GC-MS) allowed the quantitative and qualitative detection of 22 compounds in the sample. Aldehydes were the main chemical group in the sample and followed by aromatic alcohols and lactone. Aroma extract dilution analysis was implemented for the specification of key odourants of B. crataegina. In total, eight key odourants were detected in the extract of the sample, using GC-MS-Olfactometry and aldehydes were the leading chemical group. The key odourants, found to be contributing to the overall aroma in B. crataegina, were nonanal (FD = 1024; green, flowery), hexanal (FD = 512; green) and linalool (FD = 256; flowery, rose) because of high FD factors. [GRAPHICS] .