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    Mechanical and tribological performances of polypropylene composites containing multi-walled carbon nanotubes
    (Inderscience Enterprises Ltd, 2014) Dike, Ali Sinan; Mindivan, Ferda; Mindivan, Harun
    Polypropylene (PP)-based composites filled with as-received carbon nanotubes (ASCNTs) and purified carbon nanotubes (PCNTs) at different weight percentages were prepared using twin-screw extrusion and injection moulding. The effects of CNT content and purification procedure on the mechanical properties and wear resistance were examined. The results showed that microhardness, Young's modulus, tensile strength, and wear resistance values of the composites increased after purification procedure compared to the ASCNT-based composites, due to the fact that the enhanced interactions between CNT and PP improved the load transfer efficiency from PP to CNTs. For the composites prepared with both ASCNT and PCNT, as the loading of the CNTs increased, improved mechanical properties and wear resistance were observed. However, the mechanical properties and wear resistance decreased when the CNT content exceeded 0.8 wt.% due to agglomeration of CNTs.
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    Mechanical, thermal, and micro- and nanostructural properties of polyvinyl chloride/graphene nanoplatelets nanocomposites
    (John Wiley and Sons Inc, 2020) Mindivan, Ferda; Göktaş, Meryem; Dike, Ali S.
    This article describes micro- and nanostructural, mechanical, and thermal properties of nanocomposites based on polyvinyl chloride (PVC) and graphene nanoplatelets (GNP). The primary objective of this study was to extend restricted application area of PVC due to its low thermal stability and limited mechanical properties. GNP-filled PVC nanocomposites were prepared (0, 0.1, 0.3, 0.5, and 1.0 wt%) by colloidal blending method and characterized in detail. The highest value of the tensile strength 13.73 MPa (an increase of 58%) and the highest value of microhardness 83.42 MPa (an increase of 82%) were obtained with GNP loading content of 0.5 wt% compared neat PVC. The mechanical properties started to decrease at loading higher than 0.5 wt%; however, the thermal properties continued to increase. The differential scanning calorimetry and Fourier transform infrared analysis results of this nanocomposite confirmed that the increase in glass transition temperature from 34.99°C to 44.36°C and the decrease in the height of functional groups peaks proved to prevented segmental relaxation and intermolecular vibrations of PVC, respectively. Thermogravimetric analysis results were showed that the percentage of carbonaceous residue increased to 15.77% by increasing the GNP content from 0.1 to 0.5 wt%. As a result, the best GNP loading was at 0.5 wt% for PVC/GNP nanocomposites where mechanical and thermal properties of PVC/GNP were both enhanced. © 2020 Society of Plastics Engineers