Yilmaz, S.McGlynn, E.Bacaksiz, E.Bogan, J.2025-01-062025-01-0620140947-83961432-063010.1007/s00339-013-7817-x2-s2.0-84897912189https://doi.org/10.1007/s00339-013-7817-xhttps://hdl.handle.net/20.500.14669/3289In this work, the structural, chemical and magnetic properties of ZnO:Mn nanorods were investigated. Firstly, well-aligned ZnO nanorods with their long axis parallel to the crystalline c-axis were successfully grown by the vapor phase transport technique on Si substrates coated with a ZnO buffer layer. Mn metal was then diffused into these nanorods at different temperatures in vacuum. From SEM results, ZnO:Mn nanorods were observed to have diameters of similar to 100 nm and lengths of 4 mu m. XPS analysis showed that the Mn dopant substituted into the ZnO matrix with a valence state of +2. Magnetic measurements performed at room temperature revealed that undoped ZnO nanorods exhibit ferromagnetic behavior which may be related to oxygen vacancy defect-mediated d (0) ferromagnetism. ZnO:Mn samples were seen to show an excess room temperature ferromagnetism that is attributed to the presence of oxygen vacancy defects forming bound magnetic polarons involving Mn.eninfo:eu-repo/semantics/closedAccessMn-Doped ZnoRoom-Temperature FerromagnetısmThın-FılmsMagnetıc-PropertıesRaman-ScatterıngNanopartıclesSemıconductorsTransıstorsBulkDefect-mediated ferromagnetism in ZnO:Mn nanorodsArticle3211Q2313115WOS:000333612400044Q2